You can try both platforms,it is better you try both since it's your first time, you may choose Facebook and end up going back to Twitter,so give both a try.
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Well in this case,you have to choose base on what you want to do,the two are good platform but the user interface of twitter is very easy and friendly as well,but facebook have the audience.I have a premium affiliate marketing program I want to sign up for, but I'm confused on the type of social media platform to buy ads from to promote the Affiliate marketing program. I intend to use either Facebook or twitter but I'm still doing my due diligence on which to use. So if you have any recommendation on both, you can help me out